Seite - 38 - in Advanced Chemical Kinetics

1. Introduction 1.1. Background Since their introduction around a century ago, internal combustion engines have played a key role in shaping of the modern world [1]. Because of their simplicity, ruggedness and high power/weight ratio, internal combustion engine has found wide application in transportation [2]. Though there are technologies that could theoretically provide more environmentally sound alternatives, internal combustion engines, such as fuel cells and electric vehicles, practically, cost, efficiency and power density issues, will prevent them displacing internal combustion engines in the near future. However, in recent decades, serious concerns have been raised with regard to the environmental impact of emissions arising from operation of internal combustion engines. Eventually, concerns about climate change lead to ever-stricter fuel-economy legislations [2-4]. In addition, concerns about the world’s finite oil reserves result in heavy taxation of road transport, mainly via on duty on fuel [5]. These two factors have led to massive pressure on vehicle manufacturers to research, develop and produce ever cleaner and more fuel- efficient vehicles. Ultimately, all legislations for emissions from vehicles are targeted to improve technologies to the point where an affordable, practical zero emissions vehicle (ZEV) with outstanding performance becomes a reality [6]. Even though there are many types of real ZEVs, operated by fuel cells that consume hydrogen generated from water by electricity produced from renewable sources, it is very unlikely that the resulting vehicles could even come close to meeting any of the other criteria listed above in the short and medium terms [1, 2]. For this reason, the bulk of vehicle research and devel- opment resources are still being applied to the internal combustion engines to increase their efficiency. 1.2. Homogeneous charge compression ignition (HCCI) engine The purpose of internal combustion engines is the production of mechanical power from the chemical energy contained in the fuel. This chemical energy is released by burning or oxidiz- ing the fuel inside the engine. The fuel-air mixture before combustion and burned products after combustion are the actual working fluids. The work transfers, which provide the desired power output, occur directly between these working fluids and the mechanical components of the engine. As Figure 1 shows, there are three main types of internal combustion engines: • Spark ignition (SI) engine • Compression ignition (CI) engine • Homogeneous charge compression ignition (HCCI) engine Advanced Chemical Kinetics38