Seite - 109 - in Advanced Chemical Kinetics

[5] Morton D, Cole-Hamilton DJ. Molecular hydrogen complexes in catalysis: Highly effi- cient hydrogen production from alcoholic substrates catalysed by ruthenium complexes. Journal of the Chemical Society, Chemical Communications. 1988;2(17):1154-1156. DOI: 10.1039/c39880001154 [6] Junge H, Beller M. Ruthenium-catalyzed generation of hydrogen from iso-propanol. Tetrahedron Letters. 2005;46(6):1031-1034. DOI: 10.1016/j.tetlet.2004.11.159 [7] Junge H, Loges B, Beller M. Novel improved ruthenium catalysts for the generation of hydrogen from alcohols. Chemical Communications. 2007;(5):522-524. DOI: 10.1039/ B613785G [8] Bertoli M, Choualeb A, Lough AJ, Moore B, Spasyuk D, Gusev DG. Osmium and ruthe- nium catalysts for dehydrogenation of alcohols. Organometallics. 2011;30(13):3479-3482. DOI: 10.1021/om200437n [9] Nielsen M, Kammer A, Cozzula D, Junge H, Gladiali S, Beller M. Efficient hydrogen production from alcohols under mild reaction conditions. Angewandte Chemie, Inter- national Edition. 2011;50(41):9593-9597. DOI: 10.1002/anie.201104722 [10] Spasyuk D, Gusev DG. Acceptorless dehydrogenative coupling of ethanol and hydro- genation of esters and imines. Organometallics. 2012;31(15):5239-5242. DOI: 10.1021/ om300670r [11] Morton D, Cole-Hamilton DJ. Rapid thermal hydrogen production from alcohols cata- lysed by [Rh(2,2′-bipyridyl)2]cl. Journal of the Chemical Society, Chemical Communi- cations. 1987;1(4):248-249. DOI: 10.1039/C39870000248 [12] Morton D, Cole-Hamilton DJ, Utuk ID, Paneque-Sosa M, Lopez-Poveda M. Hydrogen production from ethanol catalysed by group 8 metal complexes. Journal of the Chemical Society, Dalton Transactions. 1989;(3):489-495. DOI: 10.1039/dt9890000489. http://pubs. rsc.org/en/content/articlelanding/1989/dt/dt9890000489#!divAbstract [13] Nielsen M, Junge H, Kammer A, Beller M. Towards a green process for bulk-scale syn- thesis of ethyl acetate: Efficient acceptorless dehydrogenation of ethanol. Angewandte Chemie, International Edition. 2012;51(23):5711-5713. DOI: 10.1002/anie.201200625 [14] Sponholz P, Mellmann D, Cordes C, Alsabeh PG, Li B, Li Y, Nielsen M, Junge H, Dixneuf P, Beller M. Efficient and selective hydrogen generation from bioethanol using ruthenium pincer-type complexes. ChemSusChem. 2014;7(9):2419-2422. DOI: 10.1002/ cssc.201402426 [15] Nielsen M, Alberico E, Baumann W, Drexler H-J, Junge H, Gladiali S, Beller M. Low- temperature aqueous-phase methanol dehydrogenation to hydrogen and carbon diox- ide. Nature. 2013;495(7439):85-89. DOI: 10.1038/nature11891 [16] Bielinski EA, Förster M, Zhang Y, Bernskoetter WH, Hazari N, Holthausen MC. Base- free methanol dehydrogenation using a pincer-supported iron compound and Lewis acid co-catalyst. ACS Catalysis. 2015;5(4):2404-2415. DOI: 10.1021/acscatal.5b00137 Catalyst Kinetics and Stability in Homogeneous Alcohol Acceptorless Dehydrogenation http://dx.doi.org/10.5772/intechopen.70654 109