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percentages. Among which, 0.5 M ZnO-FA-Sep competes with the 0.5 M ZnO-FA within
10min irradiation. The slight difference in the degradation and decolorization percentages
may be due the smaller variations in theZnO crystalline sizes, BETareas andpore volumes
(DZnO=8.12nm,BET=60m
2g 1,Vpore=0.122cm 3g 1 for0.5MZnO-FAandDZnO=11.6nm,
BET = 50.2m2 g 1, Vpore = 0.097 cm
3 g 1 for 0.5MZnO) [12]. Although FA-Sep has amore
complex structure than theFAalone,ZnOnanoparticles in the ternary systemare locatedon
the external surfaces of both FAand Sep showing no preference to any of theseminerals as
detected in the SEM images.Moreover, FAaswell as Sep crystals do not agglomerate in the
ternary composite owing to theirmorphological differences in shape and sizes. This creates
uniqueness for0.5MZnO-FA-SepandenhancesdispersionofZnOnanoparticles.
4.3.3.Reusability
Furthermore, to investigate the photocatalytic stability of 0.5MZnO-FA-Sep, cyclic experi-
mentsarecarriedoutunderthesameexperimentalconditions (Figure4D).Foreachrun,0.5M
ZnO-FA-Sepis filtrated,washedandcalcinedat500 Cfor2h.After fourcycles, thepercentage
ofMOremaining in solution is found to increase onlyapproximately 2% (from15 to 17% for
decolorization process) and 3% (from 12 to 15% for degradation process). The slight incre-
ments in the percentages can be attributed to the catalyst loss during each collection and
rinsingsteps.
5.Conclusions
Aternary-supported catalyst hasbeenpreparedandcharacterizedbyXRD,BET, SEM(EDX),
XPSandDRUVtechniques.ZnOnanoparticles are found tobedispersedonbothFAandSep
minerals. Supported catalysts exhibit higher surface areas andporevolumes thanFA-Sep, FA
and 0.25 M ZnO DZnO sizes do not exhibit significant differences depending on the ZnO
loading concentrations. EDX, mapping and XPS analysis evidence the existence of ZnO
nanoparticles. Moreover, supported catalysts exhibit an absorption edge similar to 0.25 M
ZnO with a slight blue shift. High dark adsorption capacities of the supported catalysts
improve theirphotocatalytic activities,which further enhancedwith theZnOloadingconcen-
tration. The existence of both FA and Sep with different shapes and sizes decrease their
agglomerationandexposemoreof their surfaces for theadsorptionofZnOnanoparticles.
Future studies will focus on the development of new composites and their applications in
environmental issues.
Acknowledgements
This studywas supportedbyBoğaziçiUniversityResearchFoundation (ProjectNo. 17B05P4/
13021).
Advanced Chemical
Kinetics160
zurück zum
Buch Advanced Chemical Kinetics"
Advanced Chemical Kinetics
- Titel
- Advanced Chemical Kinetics
- Autor
- Muhammad Akhyar Farrukh
- Herausgeber
- InTech
- Ort
- Rijeka
- Datum
- 2018
- Sprache
- englisch
- Lizenz
- CC BY 4.0
- ISBN
- 978-953-51-3816-7
- Abmessungen
- 18.0 x 26.0 cm
- Seiten
- 226
- Schlagwörter
- Engineering and Technology, Chemistry, Physical Chemistry, Chemical Kinetics
- Kategorien
- Naturwissenschaften Chemie