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Nrr¼Ns�NintþNas (17)
whereas,Ns is thenumberof steps in thedetailedmechanismandNas is thenumberof active
sites in themechanism. Based on themolecularmatrix, themolarmasses of the components
canbedetermined fromtheatomicmasses of the elements. Theproduct of the stoichiometric
matrixSandmolecularmatrixMgives
SM¼0 (18)
Toanswer the secondpartof theabovequestion,weneed to consider all its available routes to
get thedetailedreactionmechanism.Thenacomparisonof theseroutesolutionswith thewhole
reactionmechanismallows us to give any concluding remarks, butwe believe that the result
obtainedthroughdifferent routesmaybesimilarorvarydependingonthetypeofreactions.
4.Multiroute reactionsmechanism
Tounderstand this idea, letusdiscern the four-stepreversible complexchemical reaction [3]
definedovera closed systemhaving twoavailable routes. Themechanism involves six chem-
ical substances (speciesCi) representedas (Figure3),
Figure2. Acomplex chemical reactionpasses throughdifferent transition states andadoptsdifferent completion routes
beforegiving theproducts.
Advanced Chemical
Kinetics10
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Advanced Chemical Kinetics
- Title
- Advanced Chemical Kinetics
- Author
- Muhammad Akhyar Farrukh
- Editor
- InTech
- Location
- Rijeka
- Date
- 2018
- Language
- English
- License
- CC BY 4.0
- ISBN
- 978-953-51-3816-7
- Size
- 18.0 x 26.0 cm
- Pages
- 226
- Keywords
- Engineering and Technology, Chemistry, Physical Chemistry, Chemical Kinetics
- Categories
- Naturwissenschaften Chemie