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The Reek group showed in 2016 that [Ru(salbinapht)(CO)(PiPr3)] (Figure 10) is also capable of
dehydrogenating MeOH [23]. A TOF value of 55 h−1 could be reached by a catalyst loading of
24 ppm with respect to MeOH in a 25% dioxane/75% 9:1 (v/v) MeOH/H2O mixture containing
8 M KOH and conducting the reaction at 82°C. Lowering the base concentration to 6 M and
Figure 8. Proposed catalytic cycle for MeOH reforming by Grützmacher using MeOH as substrate. Best results:
TOF = 54 h−1. TON = 540 h−1. Conversion = 90%. Yield = 84%.
Catalyst Kinetics and Stability in Homogeneous Alcohol Acceptorless Dehydrogenation
http://dx.doi.org/10.5772/intechopen.70654 103
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Advanced Chemical Kinetics
- Title
- Advanced Chemical Kinetics
- Author
- Muhammad Akhyar Farrukh
- Editor
- InTech
- Location
- Rijeka
- Date
- 2018
- Language
- English
- License
- CC BY 4.0
- ISBN
- 978-953-51-3816-7
- Size
- 18.0 x 26.0 cm
- Pages
- 226
- Keywords
- Engineering and Technology, Chemistry, Physical Chemistry, Chemical Kinetics
- Categories
- Naturwissenschaften Chemie