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of thereactivecompositebyusinghigh-energyballmilling(HEBM)inthesamebinarysystem,
one can significantly change the measured effective activation energy [20]. There are two
approaches to quantifying this effect; the first is by rigorous quantification of the already
existing structures, and the second isbyuseofmore simple, so-calledmodelmicrostructures,
typicallymanifested inreactivenanofoilswithperiodically fabricated layersof reactants.
Shuck et al. utilized two techniques for quantitativedeterminationofHEBM-producedmate-
rials [5, 157]. The first technique, X-rayNanotomography, works by passing high brilliance
X-rays through the sample and collecting the transmittedX-rays. In order to convert this 2D
projectionintothreedimensions, thesample isrotatedandthesamequalityofX-rays ispassed
throughagainandtheprojectionsatdifferentanglesarecollected; thiscollectionof imagescan
be combined, leading to a 3Dmapof the internal sample. The second technique, focused ion
beam(FIB)sectioning,usesaFIBtoseriallysectiontheHEBM-producedparticles.Theseriesof
imageswere first shear corrected, contrastnormalized, and thenalignedusinga least-squares
method, with the reconstructions shown in Figure 6. After structure analysis, Shuck and
Figure6. Reconstructed internalvolumesof thenanocomposites fordifferent time (min)ofWG: (a)10, (b) 20, (c) 30, and
(d)40 (Ni is thegrayphase,andAl is thevoid-space).Adapted fromShucketal. [5].
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Advanced Chemical Kinetics
- Title
- Advanced Chemical Kinetics
- Author
- Muhammad Akhyar Farrukh
- Editor
- InTech
- Location
- Rijeka
- Date
- 2018
- Language
- English
- License
- CC BY 4.0
- ISBN
- 978-953-51-3816-7
- Size
- 18.0 x 26.0 cm
- Pages
- 226
- Keywords
- Engineering and Technology, Chemistry, Physical Chemistry, Chemical Kinetics
- Categories
- Naturwissenschaften Chemie