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Materials  2016,  9,  171  6  of  9    Figure  3.  The  AFM  surface  topography  and  phase  images  of  the  PTB7:PC71BM  films  with/without    3  v%  DIO  and/or  1  wt  %  PS.  In  order  to  further  investigate  the  effects  of  additive  on  the  charge  carrier  transport,  the  hole‐only  devices  have  been  fabricated  based  on  pristine  PTB7  films  and  blend  PTB7:PC71BM  films  with/without  additives,  respectively.  High‐work‐function  material  gold  (Au)  is  used  as  the  cathode  to  block  the  back  injection  of  electrons.  The  dark  J‐V  curves  of  the  hole‐only  devices  with  the  configuration  of  ITO/PEDOT:PSS/PTB7/Au  and  ITO/PEDOT:PSS/PTB7:PC71BM/Au  are  measured  and  shown  in  Figure  4.  The  hole  transport  through  the  polymer  film  is  limited  due  to  the  accumulation  of  space  charge  when  a  sufficient  voltage  is  applied  to  this  hole‐only  device.  The  space  charge  limited  current(SCLC)  is  described  by  the  equation  [29,30]:    2 2 9 9 V VJ Figure 3. The AFM surface topography and phase images of the PTB7:PC71BM filmswith/without3v%DIOand/or1wt%PS. 8
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Photovoltaic Materials and Electronic Devices
Title
Photovoltaic Materials and Electronic Devices
Author
Joshua M. Pearce
Editor
MDPI
Location
Basel
Date
2016
Language
English
License
CC BY-NC-ND 4.0
ISBN
978-3-03842-217-4
Size
17.0 x 24.4 cm
Pages
216
Keywords
Perovskite, Plasmonics, Nanostructured Materials, Anti-Reflection Coatings, Transparent Conductive Oxides, Amorphous Silicon, Dye-sensitized Solar Cells (DSSCs) Materials, Organic Photovoltaic Materials, Solar Energy Materials
Categories
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Technik
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